Hydrated HCl Complexes, (HCl)M(H2O)N, in Helium Nanodroplets: OH Stretching Modes

Details Hydrated HCl Complexes, (HCl)M(H2O)N, in Helium Nanodroplets: OH Stretching Modes Hydrated HCl Complexes, (HCl)M(H2O)N, in Helium Nanodroplets: OH Stretching Modes

Jun 2010

adsabs.harvard.edu/cgi-bin/nph-data_query?bibcode=2010mss..confefb09l&link_type=abstract

"International Symposium On Molecular Spectroscopy, 65th Meeting, Held 21-25 June, 2010 at Ohio State University. http://molspec

Computer Science

Matrix/Condensed Phase

Scientific paper

Infrared laser spectroscopy has been used to characterize the solvation of HCl with small number of water molecules in helium nanodroplets. Complexes of (HCl)M(H2O)N with m = 1 -- 3 and n = 1 -- 3 have been identified in the free OH stretching and bonded OH spectral range of 3000 -- 3900 cm-1. The assignment of the infrared vibrational bands of the clusters is aided by pick-up pressure dependence experiments and ab initio calculations.

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