High resolution spectroscopy of 13CH3OH around the 10R(20) CO2 laser emission: new FIR laser lines, frequency measurements and assignments.

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Infrared Spectra: Methanol

Scientific paper

The authors investigated the IR absorption spectrum of 13CH3OH around the frequency of the 10R(20) CO2 laser line. They found two absorption lines which can be excited by 10R(20) and studied the FIR laser emissions excited by this pump line using a waveguide CO2 laser of 300 MHz tunability. The authors report two new FIR laser lines of large offset, not previously observed due to their weakness and closeness to other stronger lines. The authors measured the frequencies of five FIR laser lines for the first time by an accurate heterodyne technique and present the complete assignments of the IR-FIR laser systems relative to this pump line. Furthermore they present new frequency values for two FIR laser lines whose frequencies had been previously wrongly measured.

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