High resolution absorption cross-sections and band oscillator strengths of the Schumann-Runge absorption bands of isotopic oxygen, (O-18)2, at 79 K

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Absorption Cross Sections, High Resolution, Oscillator Strengths, Oxygen Isotopes, Schumann-Runge Bands, Absorption Spectra, Electrophotometers, Low Temperature, Nasa Programs

Scientific paper

Cross-sections of (O-18)2 at 79 K have been obtained from photoabsorption measurements at various pressures throughout the wavelength region 177.8-197.8 nm with a 6.65 m photoelectric scanning spectrometer equipped with a 2400 lines/mm grating and having an instrumental width (FWHM) of 0.0013 nm. The measured absorption cross-sections of the Schumann-Runge bands (14,0) through (2,0) are, with the exception of the (12,0) band, independent of the instrumental width. The measured cross-sections are presented graphically here and are available at wavenumber intervals of about 0.1/cm as numerical compilations stored on magnetic tape. Band oscillator strengths of those bands have been determined by direct numerical integration of the measured absolute cross-sections and are in excellent agreement with these theoretically calculated values.

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