High-lying bound Rydberg states of excited Hg(6s6p 3P1) atoms from two-color resonance ionization mass spectroscopy

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Multiphoton Ionization And Excitation To Highly Excited States, Oscillator Strengths, Lifetimes, Transition Moments, Properties Of Atoms, Mass Spectrometry

Scientific paper

Mercury isotopes are investigated with two-color resonance ionization mass spectroscopy (RIMS). Isotope shifts, hyperfine structure splittings, and the lifetime of the intermediate 6s6p 3P1 state are determined by RIMS. Ion yields at the threshold region in various static electric fields are measured in order to determine an extrapolated ionization energy value at zero field strength. New energy values for high-lying bound 6s nd 3D (21

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