High accuracy molecular line lists for exoplanetary atmospheres

Statistics – Computation

Scientific paper

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Scientific paper

ABSTRACT Water, carbon monoxide, methane and ammonia are major constituents exoplanetary atmospheres. Measurements of the relative abundances of these species are capable of yielding information about physical conditions, including: temperature, pressure, thermal profile and metallicity. Modern observational techniques and instrumentation mean that in principle, we now have the capability to detect these molecules in the emission and absorption spectra of transiting exoplanets. However, in order to be able to interpret these data, robust atmospheric models and complete and accurate molecular line lists are required. Our team at UCL is a world leader in the computation of molecular spectroscopic line lists. The BT2 water line list [1], which contains over 500 million transitions, was used in the first secure detection of H2O in the atmosphere of a transiting exoplanet [2]. We are currently computing a line list for NH3, which is a considerably more dif cult task as the molecule has nine degrees of internal freedom (H2O has six). In this paper, we will discuss the ab initio computation of ro-vibrational molecular spectra and their application in exoplanetary studies. References [1] Barber R. J., Tennyson J., Harris G. J., Tolchenov R., 2006, MNRAS, 368, 1087 [2] Tinetti G. et al., 2007, Nature, 448, 169

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