HgCdTe fabrication using directed energy techniques

Computer Science

Scientific paper

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Cadmium Tellurides, Electron Irradiation, Epitaxy, Evaporation, Fabrication, Mercury Compounds, Single Crystals, Thin Films, Crystal Growth, Electron Beams, Infrared Detectors, Stoichiometry, Substrates

Scientific paper

The goal of this research is to produce large-area, thin-film, single crystal mercury cadmium telluride material for infrared detectors. The successful approach is to (1) evaporate cadmium telluride in an enclosed furnace on insulating crystalline substrates (hot wall epitaxy), (2) melt a thin surficial layer by pulsed electron beam irradiation to improve morphology, and (3) convert to mercury cadmium telluride by evaporation and diffusion at constant temperature. The final result is a single crystal film of Hg (sub 1-x) Cd sub x Te, 30 microns thick and 0.5 inch square, with a compositional variation of x less than + or - 0.0007. Films of up to 20 microns thick, 1 inch o.d., single crystal (but twinned) CdTe were produced by the first process. These faceted films were smoothed without change of surface stoichiometry or structure by the second process. Evaporation of HgTe at less 0.5 atm Hg overpressure onto the CdTe film produced the final result on mica or quartz substrates. Electron mobility at 77 K was as high as 1.5 x 10 to the 5th power sq cm/V-s in the final samples.

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