HD+ photodissociation in the scaled coordinate approach

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Diffuse Spectra, Predissociation, Photodissociation, Strong-Field Excitation Of Optical Transitions In Quantum Systems, Multiphoton Processes, Dynamic Stark Shift, Other Multiphoton Processes, Autoionization, Photoionization, And Photodetachment

Scientific paper

The scaled coordinate approach is applied to the problem of H D+ photodissociation in a short, intense, infrared laser pulse. Two- and three-dimensional models for the molecule aligned in the field of a linearly polarized laser are studied. Scaling allows substantial improvements in the numerical accuracy and provides a simple way to calculate the fragments’ energy spectra.

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