H2O under Extreme Conditions

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3616 Hydrothermal Systems (0450, 1034, 3017, 4832, 8135, 8424), 3672 Planetary Mineralogy And Petrology (5410), 3924 High-Pressure Behavior, 3934 Optical, Infrared, And Raman Spectroscopy, 3954 X-Ray, Neutron, And Electron Spectroscopy And Diffraction

Scientific paper

Water consists of the first and third most abundant elements in the solar system and is ubiquitous in the cosmos. However, knowledge of its behavior over the broad range of P-T conditions relevant to the entire solar system is only just now becoming available. Advances in high P-T techniques, including spectroscopies, x-ray and neutron scattering, and a variety of computational theory are providing an important baseline for planetary models. This new information includes stable and metastable transitions, phase relations, equations of state, vibrational dynamics, and structures of solid and fluid phases over a broad range of conditions. The P-T phase diagram of H2O has been the subject of a number of recent studies. Measurements of the melting curve using spectroscopic and x-ray diffraction reveal a steep rise in the melting temperature of above the triple point near 35 GPa and 1040 K. The melting line may intersect the isentropes of Neptune and Uranus, giving rise the stratified layers of solid ice at depth within these planets. The high melting temperature of H2O may also ihave important implications for the Earth's lower mantle above 60 GPa. The presence of any free H2O would result in changes in physical properties, such as viscosity, in the mid lower mantle . The low P-T properties of H2O are particularly important for understanding processes on planetary bodies such as satellites of the outer solar system. Studies below 10 GPa and at variable temperatures (to 10 K) reveal metastable transitions, including both crystalline and high-density amorphous forms, relevant to planetary impacts. There are important effects of solutes on the low P-T properties of these metastable phases. Salt solutions stabilize the amorphous phases and the formation of low-temperature clathrates with gas molecules can form, providing a mechanism for incorporation of gases in growing planetary bodies.

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