Ground-state rotational constants of /C-13/H3D

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Deuterium Compounds, Ground State, Methane, Molecular Rotation, Vibrational Spectra, Electron Transitions, Jupiter Atmosphere, Molecular Oscillations, Saturn Atmosphere

Scientific paper

Rotational constants for the vibrational ground state of (C-13)H3D, which has been detected in the atmospheres of Jupiter and Saturn, are reported. High-resolution spectra of monodeuteromethane were obtained in the region 1800 to 2500 kaysers by a vacuum Fourier interferometer, and the values of the rotational constants B0, D0J, D0JK, H0JJJ, H0JJK and H0JKK were calculated by an analysis of ground-state combination differences in the nu 2(A1) band. The calculated frequency and intensity of this transition are found to be in agreement with the observed values.

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