Franck-Condon factors and r-centroids for the E1Σ+ - X1Σ+ bands of SiS and SiSe.

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Molecular Processes

Scientific paper

By using the computer program TRAPRB developed by Jarmain and McCallum, Franck-Condon factors and r-centroids have been calculated for the E1Σ+ - X1Σ+ bands of the SiS and SiSe radicals. Intensities of these bands have been visually estimated from the emission spectra photographed on a 3.4 m Ebert grating spectrograph (5 Å/mm). A comparison of the Franck-Condon factors with these estimated intensities shows reasonable agreement.

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