Fourier transform jet emission spectroscopy of the B2Σ+-X2Σ+ transition of CN

Details Fourier transform jet emission spectroscopy of the B2Σ+-X2Σ+ transition of CN Fourier transform jet emission spectroscopy of the B2Σ+-X2Σ+ transition of CN

Feb 1992

adsabs.harvard.edu/cgi-bin/nph-data_query?bibcode=1992jmosp.151..459p&link_type=abstract

Journal of Molecular Spectroscopy, Volume 151, Issue 2, p. 459-473.

Mathematics

53

Scientific paper

The violet (B2Σ+-X2Σ+) system of the CN molecule was produced in a jet-cooled, coronaexcited, supersonic expansion of helium using methyl azide and diazoacetonitrile as precursor molecules. This spectrum was also excited in a Cossart source with a trace of methane in argon. The spectra were recorded with the McMath Fourier transform spectrometer of the National Solar Observatory. In the present work, the rotational structure of the 0-0 through 7-7 and 1-0 through 9-8 vibrational bands was analyzed.
Current address: Department of Chemistry, University of New Mexico, Albuquerque, NM 87131.

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