Formation and Identification of Interstellar Molecule Linear C5H from Photolysis of Methane Dispersed in Solid Neon

Astronomy and Astrophysics – Astronomy

Scientific paper

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Astronomical Data Bases: Miscellaneous, Ism: Molecules, Molecular Data, Stars: Carbon

Scientific paper

Photolysis of methane dispersed (1/1000) in solid Ne at 3 K with vacuum-ultraviolet light from a synchrotron produced infrared absorption lines of several products, including new lines at 3319.3 and 1955.5 cm-1. Based on experiments with isotopic labeling and results of quantum-chemical calculations, these lines are assigned to the C-H stretching and C=C stretching modes, respectively, of interstellar molecule linear C5H radicals.

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