Foreign-gas pressure broadening and shift of ammonia transition lines in the nu-2 vibrational bands

Computer Science

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Ammonia, Frequency Shift, Laser Spectroscopy, Pressure Broadening, Spectrophotometers, Vibrational Spectra, Carbon Dioxide, Helium, Hydrogen, Nitrogen, Semiconductor Lasers

Scientific paper

Foreign-gas broadening and shift have been measured for transitions in the nu-2, 2nu-2, and nu-4 bands of ammonia using a diode laser spectrophotometer. The measurements were performed by using foreign-gases such as CO2, N2, air, H2, and He at room temperature. The pressure-broadening and shift coefficients may be useful in modeling planetary atmospheres and the recently developed infrared ammonia laser. The experimental results are compared with the Anderson-Tsao-Curnutte theory for broadening CO2 and N2, which have large quadrupole moments. The agreement is satisfactory on the average.

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