Flux pinning, granularity and the irreversibility line of the high-Tc superconductor HgBa2CuO(4+x)

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Copper Oxides, Flux Pinning, High Temperature Superconductors, Mercury Oxides, Mixed Oxides, Barium Oxides, Current Density, Electron Microscopy, Grain Size, Magnetization, Stoichiometry

Scientific paper

The paper describes the preparation of the high-Tc superconductor HgBa2CuO(4+x) (Hg-1201) and presents results of its characterization in terms of flux pinning, granularity, and the irreversibility field, H*(T), using X-ray, SEM, TEM, and magnetization measurements. It is found that the H*(T) of this compound is significantly higher than for the two- and three-copper-layer Bi-Sr-Ca-Cu-O compounds but lower than for YBaCu3O7, and that the low-temperature flux pinning is strong. However, Hg-1201 is electromagnetically granular in all but very weak fields, while the requirements of a high-Tc superconductor for large-scale applications emphasize the availability of superconductor in polycrystalline form which is not electromagnetically granular. It is suggested that a high degree of grain alignment might to remove this granularity.

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