Fluid mixtures in the C---H---O system at high pressure and temperature

Details Fluid mixtures in the C---H---O system at high pressure and temperature Fluid mixtures in the C---H---O system at high pressure and temperature

Feb 1988

adsabs.harvard.edu/cgi-bin/nph-data_query?bibcode=1988gecoa..52..505s&link_type=abstract

Geochimica et Cosmochimica Acta, vol. 52, Issue 2, pp.505-512

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Scientific paper

Interaction energy parameters ( W ij ) for polar-polar and polar-nonpolar mixtures of gases (H 2 , O 2 , CO 2 , H 2 O, CO and CH 4 ) have been calculated using the Kihara and Stockmayer potentials, respectively. Using the mixing rules of averaging for dimensional properties and of geometric mean for potential parameters, W ij data are calculated for binary mixtures. The interaction parameters are used with the van Laar solution model and are found to reproduce the experimental binary mixing data well. The mixing model has been tested against experimental phase equilibrium data on solid-fluid reactions. Examples of some applications in the systems Mg-Si-O-H, Fe-O and C-H-O are presented.

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