Mathematics – Logic
Scientific paper
Jan 1993
adsabs.harvard.edu/cgi-bin/nph-data_query?bibcode=1993gecoa..57...89n&link_type=abstract
Geochimica et Cosmochimica Acta, vol. 57, Issue 1, pp.89-103
Mathematics
Logic
Scientific paper
Fluid evolution during emerald mineralization at the Gravelotte emerald mine has been studied by microthermometry and laser Raman microprobe spectrometry. The emeralds and associated phenakites occur on the flanks of a highly metasomatised albitite pegmatoid body and in the biotite schists at and near its contact. The fluids lie in the H 2 O-CH 4 -CO 2 -NaCl system and four types of inclusions are characterised based on time of trapping and fluid contents. The earliest type 1 inclusions, found in phenakites and the emeralds which formed from them, are low salinity (<6 wt% NaCl) with up to 18 mol% CH 4 . The carbonic phase contains over 93 mol% CH 4 and variable small amounts of CO 2 , C 2 H 6 , N 2 , and H 2 S. The solvus crest for this system lies at 400°C, closer to the H 2 O end of the join. With time the fluids become less CH 4 rich and more saline. The type 2 fluids are highly variable in both CH 4 -CO 2 contents and salinity, reflecting mixing of type 1 fluids with higher salinity brines. The late type 3 and 4 inclusions are CH 4 -CO 2 -free high salinity inclusions with up to 38 wt% NaCl. Trapping conditions for the type 1 fluids were around 450-500°C and 4 kb based on model isochores and geologic evidence. During the trapping of type 2 inclusions, fluid pressures probably fluctuated due to opening and resealing of fractures. Approximate P - T ranges of trapping for these and other later inclusions have been defined, minimum trapping temperatures for types 2, 3, and 4 being, respectively, 250, 150, and 240°C, and pressures in the range of 1-4 kb. Calculations of f O 2 show an initial low f O 2 between QFM and the synthetic graphite-CH 4 buffer for the type 1 fluids. This rises to above QFM in the later stages. Such low initial values are uncharacteristic of granitic pegmatite systems, and it is suggested that the phenakites formed in the post-magmatic stage of alkali metasomatism when the albitization took place. In the later stages, phenakite was converted to emerald as alumina activities in the system increased. Concomitantly higher salinity brines, at least some of which are probably related to regional metamorphism in the area, were trapped under higher f O 2 conditions. Metasomatic exchange with the mafic host rocks also increased as evidenced by the incorporation of Cr in the late emeralds. The energy necessary for the continuous growth of the later emeralds was probably supplied by regional metamorphism.
Morteani Giulio
Nwe Yin Yin
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