Computer Science
Scientific paper
Jun 2011
adsabs.harvard.edu/cgi-bin/nph-data_query?bibcode=2011mss..confeti07o&link_type=abstract
"International Symposium On Molecular Spectroscopy, 66th Meeting, Held 20-24 June, 2011 at Ohio State University. http://molspec
Computer Science
Infrared/Raman
Scientific paper
In this study, an IR-UV fluorescence depletion scheme is employed to record rotationally resolved IR spectra in the CN overtone region of CN-Ne, CN-Ar, and CN-H2/D2 using previously reported B-X electronic transitions. The resulting IR spectra are fit to yield band origins and rotational constants for the lower and upper states. The band origins for all four species are shifted only slightly from the CN monomer overtone stretch, which reflects the weak nature of the van der Waals interactions. In the case of CN-Ar and CN-D2, the derived rotational constants are consistent with equilibrium distances from ab initio potential energy surfaces. However, for CN-Ne and CN-H2, Coriolis coupling between nearby hindered rotor states complicates the rotational analysis. Ongoing work using an alternate IR-UV double-resonance technique will help elucidate the nature of the interaction and the average configuration of the ground states of the four species.
Beames Joseph M.
Lester Marsha I.
O'Donnell Bridget A.
Ting Melodie
No associations
LandOfFree
First Infrared Spectra of Cn-Rare Gas and CN-H2/D2 Complexes via Ir-Uv Fluorescence Depletion Spectroscopy does not yet have a rating. At this time, there are no reviews or comments for this scientific paper.
If you have personal experience with First Infrared Spectra of Cn-Rare Gas and CN-H2/D2 Complexes via Ir-Uv Fluorescence Depletion Spectroscopy, we encourage you to share that experience with our LandOfFree.com community. Your opinion is very important and First Infrared Spectra of Cn-Rare Gas and CN-H2/D2 Complexes via Ir-Uv Fluorescence Depletion Spectroscopy will most certainly appreciate the feedback.
Profile ID: LFWR-SCP-O-1001391