First composition measurements of positive ions in the upper troposphere

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Atmospheric Composition, Mass Spectroscopy, Molecular Ions, Positive Ions, Tropospheric Radiation, Airborne Equipment, Flight Tests, Mass, Mass Spectrometers

Scientific paper

First mass-spectrometric composition measurements of atmospheric ions between 3250 and 11700 m altitude are reported. They reveal the presence of very massive cluster ions, the majority of which cannot be attributed to a single hydrated ion family like, for example, H(+)(H2O)n. The observed fraction of very massive ions increases with decreasing altitude. Masses as large as about 540 amu were observed at 8200 m altitude. Implications of the observations for ion and nucleation processes are discussed.

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