Far-Infrared Synchrotron-Based Spectroscopy of Furan: Analysis of the ν14-ν11 Perturbation and the ν18 and ν19 Levels

Details Far-Infrared Synchrotron-Based Spectroscopy of Furan: Analysis of the ν14-ν11 Perturbation and the ν18 and ν19 Levels Far-Infrared Synchrotron-Based Spectroscopy of Furan: Analysis of the ν14-ν11 Perturbation and the ν18 and ν19 Levels

Jun 2011

adsabs.harvard.edu/cgi-bin/nph-data_query?bibcode=2011mss..conferg14t&link_type=abstract

"International Symposium On Molecular Spectroscopy, 66th Meeting, Held 20-24 June, 2011 at Ohio State University. http://molspec

Other

Infrared/Raman

Scientific paper

The ν14 vibrational level of furan lies 603 Cm-1 above the ground vibrational state. It is the lowest lying vibrational level for which a transition from the ground state is allowed. Other groups have conducted rotational analyses on fundamental bands of furan at 745 Cm-1 (ν13), 995 Cm-1 (ν7) and at 1067 Cm-1 (ν6). We have taken the rotationally resolved spectrum of the c-type ν14 band at the Canadian Light Source synchrotron with a Bruker IFS125HR Fourier transform spectrometer operating at 0.00096 Cm-1 resolution, and have found it to be perturbed by the ν11 band at 600 Cm-1, for which transitions from the ground vibrational state are forbidden. By taking the spectra of the b-type ν18 fundamental band and of the very weak c-type ν18- ν11 band we have been able to analyze the ν14- ν11 perturbation. We have also analyzed the spectrum of the b-type ν19 fundamental band. [2]{B. Pankoke, K. M. T. Yamada, G. Winnewisser, Z. Naturforsch. A 48 (1993) 1193-1202.
[3]A. Mellouki, M. Herman, J. Demaison, B. Lemoine, L. Margulès, J. Mol. Spectrosc. 198 (1999) 348-357.
[4]A. Mellouki, J. Vander Auwera, J. Demaison, M. Herman, J. Mol. Spectrosc. 209 (2001) 136-138.

Affiliated with

Also associated with

No associations

Rating

Far-Infrared Synchrotron-Based Spectroscopy of Furan: Analysis of the ν14-ν11 Perturbation and the ν18 and ν19 Levels does not yet have a rating. At this time, there are no reviews or comments for this scientific paper.

If you have personal experience with Far-Infrared Synchrotron-Based Spectroscopy of Furan: Analysis of the ν14-ν11 Perturbation and the ν18 and ν19 Levels, we encourage you to share that experience with our LandOfFree.com community. Your opinion is very important and Far-Infrared Synchrotron-Based Spectroscopy of Furan: Analysis of the ν14-ν11 Perturbation and the ν18 and ν19 Levels will most certainly appreciate the feedback.

Rate now

Comments { 0 }

Profile ID: LFWR-SCP-O-1000568