Experimental determination of the 1 sigma(+) state electron-dipole-moment function of carbon monoxide up to a large internuclear separation

Astronomy and Astrophysics – Astrophysics

Scientific paper

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Astrophysics, Carbon Monoxide, Dipole Moments, Electric Dipoles, Stellar Spectra, Abundance, Fourier Transformation, Interferometers, Least Squares Method, Vibration, Wave Functions

Scientific paper

Experimental intensity information is combined with numerically obtained vibrational wave functions in a nonlinear least squares fitting procedure to obtain the ground electronic state electric-dipole-moment function of carbon monoxide valid in the range of nuclear oscillation (0.87 to 1.01 A) of about the V = 38th vibrational level. Mechanical anharmonicity intensity factors, H, are computed from this function for delta V + = 1, 2, 3, with or = to 38.

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