Exact trajectory in semiclassical line broadening and line shifting calculation test for H2-He Q(1) line.

Details Exact trajectory in semiclassical line broadening and line shifting calculation test for H2-He Q(1) line. Exact trajectory in semiclassical line broadening and line shifting calculation test for H2-He Q(1) line.

Jan 1999

adsabs.harvard.edu/cgi-bin/nph-data_query?bibcode=1999jqsrt..61...19j&link_type=abstract

Journal of Quantitative Spectroscopy and Radiative Transfer, vol. 61, issue 1, pp. 19-24

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Molecular Processes: Line Broadening

Scientific paper

The semiclassical model RB (Robert and Bonamy, 1979) for calculation of line width and line shift has been used in many applications. It contains an approximate "parabolic" trajectory. Bykov et al. (1992) have recently proposed an analytical expression for an exact treatment of the classical path. This paper analyses the consequence of introducing the exact trajectory within the RB model for the H2-He Q(1) line chosen as a simple test. Moreover, a comparison with results of exact close-coupling calculations is also given for this molecular system.

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