Evidence for a Non-Planar C=(CCC) Structure in Hexafluoroisobutene and Hexafluoroacetone Imine: a Pure Rotational Spectroscopic Study

Details Evidence for a Non-Planar C=(CCC) Structure in Hexafluoroisobutene and Hexafluoroacetone Imine: a Pure Rotational Spectroscopic Study Evidence for a Non-Planar C=(CCC) Structure in Hexafluoroisobutene and Hexafluoroacetone Imine: a Pure Rotational Spectroscopic Study

Jun 2011

adsabs.harvard.edu/cgi-bin/nph-data_query?bibcode=2011mss..confewh14g&link_type=abstract

"International Symposium On Molecular Spectroscopy, 66th Meeting, Held 20-24 June, 2011 at Ohio State University. http://molspec

Computer Science

Microwave

Scientific paper

The pure rotational spectra of the parent and all 13C isotopologues of hexafluoroisobutene, (CF_3)_2C=CH_2, have been recorded using chirped pulse Fourier transform microwave spectroscopy. The spectra observed consist of only b-type transitions all of which are doubled by between ≈ 1 MHz to 60 MHz. This doubling phenomena may be rationalized by the assumption that the methylene carbon is slightly out of the plane formed by the remaining carbons, similiar to that observed in methylene cyclobutane. For the parent species 235 transitions have been fitted simultaneously using rotational constants, centrifugal distortion constants, the Coriolis coupling constant FAc, and the vibrational energy spacing ΔE01. The results are compared to those recently obtained for the related species hexafluoroacetone imine, (CF_3)_2C=NH.
W. Lin, J. A. Gayle, W. C. Pringle, and S. E. Novick J. Mol. Spectrosc. 251, 210-216, 2008.

Affiliated with

Also associated with

No associations

Rating

Evidence for a Non-Planar C=(CCC) Structure in Hexafluoroisobutene and Hexafluoroacetone Imine: a Pure Rotational Spectroscopic Study does not yet have a rating. At this time, there are no reviews or comments for this scientific paper.

If you have personal experience with Evidence for a Non-Planar C=(CCC) Structure in Hexafluoroisobutene and Hexafluoroacetone Imine: a Pure Rotational Spectroscopic Study, we encourage you to share that experience with our LandOfFree.com community. Your opinion is very important and Evidence for a Non-Planar C=(CCC) Structure in Hexafluoroisobutene and Hexafluoroacetone Imine: a Pure Rotational Spectroscopic Study will most certainly appreciate the feedback.

Rate now

Comments { 0 }

Profile ID: LFWR-SCP-O-1001766