Estimating groundwater discharge into the northeastern Gulf of Mexico using radon-222

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Submarine groundwater discharge (SGD) may provide important chemical constituents to the ocean, but the dispersed nature of this process makes locating and quantifying its input extremely difficult. Since groundwater contains 3-4 orders of magnitude greater radon than seawater, 222Rn may be a useful tracer of this process if all other sources of radon to bottom waters can be evaluated. We report development of a SGD tracing tool based on radon inventories in a coastal area of the northeastern Gulf of Mexico. We evaluated factors that influence the concentration of radon in the water column (i.e., production-decay, horizontal transport, and loss across the pycnocline) using a linked benthic exchange-horizontal transport model. Total 222Rn benthic fluxes (>= 2420 dpm m-2 day-1) measured with in situ chambers are of the magnitude required to support measured sub-pycnocline 222Rn inventories, while estimates of molecular diffusion show that this input is relatively small (<= 230 dpm m-2 day-1). Using this model approach, together with measurements of the radon inventory, we estimated a regional subsurface fluid flow ranging from 180 to 710 m3 sec-1 into the 620 km2 study area. This discharge, equivalent to an upward advective velocity of approximately 2-10 cm day-1 dispersed over this entire study area, is equivalent to approximately 20 first magnitude springs.

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