Equation of state of ammonia-water liquid - Derivation and planetological applications

Mathematics – Logic

Scientific paper

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Ammonia, Equations Of State, Planetary Geology, Planetology, Water, Density Distribution, Least Squares Method, Morphology, Tectonics, Thermal Expansion

Scientific paper

The present least-squares fit calculation of the equation of state for ammonia-water liquid has yielded results for the zero-100 wt pct NH3, 170-300 K temperature, and zero-10 kb pressure parameter ranges. In conjunction with solid density and thermodynamic measurements, the present calculated and measured liquid densities are used to yield estimates of density and thermal expansion at 1 bar for the solid phases of ammonia's monohydrate, dihydrate, and hemihydrate between absolute zero and their respective melting points. Attention is given to the implications for icy satellite morphologic and tectonic forms of peritectic ammonia-water liquid that is neutrally buoyant relative to the corresponding solid phases.

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