Elementary sulfur in the Venus troposphere /physical-chemical analysis/

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Atmospheric Composition, Sulfur, Troposphere, Venus Atmosphere, Hydrogen Sulfide, Kinetic Theory, Photochemical Reactions, Sulfur Dioxides, Venus Clouds

Scientific paper

The phase diagram of sulfur is analyzed, and kinetic calculations and estimations of the growth and vaporization rate of condensed sulfur phases in terms of the P-T parameters of the Venus cloud cover are carried out. A conclusion is made as to the possible existence of crystalline (orthorhombic) and liquid (metastable) sulfur drops. The source of the drops is assumed to be gaseous SO2, which undergoes a thermochemical reduction in interaction with carbon monoxide in the near-surface layer of the troposphere. The photochemical oxidation of H2S and COS above the atmospheric cloud deck is not excluded. An estimation of the possible concentration of aerosol sulfur particles in the Venus cloud layer is given.

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