Electronic Spectrum of IO- in Solution

Details Electronic Spectrum of IO- in Solution Electronic Spectrum of IO- in Solution

Jul 1965

adsabs.harvard.edu/cgi-bin/nph-data_query?bibcode=1965natur.207..185h&link_type=abstract

Nature, Volume 207, Issue 4993, pp. 185-186 (1965).

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Scientific paper

COMPOUNDS of iodine in the +1 oxidation state are unstable in aqueous solution, and for this reason their chemistry is still not clearly defined. Recording the absorption spectrum of IO- should be helpful for a systematic investigation of this group. Conflicting reports have been published on this subject1,2. Apart from the instability of IO-, the main difficulty arises from the overlap of its spectrum with that of other iodine compounds, in particular that of I3-. High alkalinity and low I- concentration are desirable for suppressing the formation of I3- and other +1 iodine compounds as HIO, I2OH- I2O = (ref. 1). Here we report the results of a spectrophotometric examination of iodine in highly concentrated alkali solutions.

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