Electric Dipole Moment of Nickel Carbonyl

Details Electric Dipole Moment of Nickel Carbonyl Electric Dipole Moment of Nickel Carbonyl

Aug 1932

adsabs.harvard.edu/cgi-bin/nph-data_query?bibcode=1932natur.130..314s&link_type=abstract

Nature, Volume 130, Issue 3278, pp. 314-315 (1932).

Mathematics

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2

Scientific paper

We have recently determined the total and the electron polarisations (the latter as the molecular refractivity for the mercury green line 5461) of nickel carbonyl in carbon tetrachloride solution at 0° C., and found values of 39.5 c.c. and 37.3 c.c. respectively. The latter value is somewhat higher than that of 355 c.c. calculated from the data of Mond and Nasini,1 who used the pure substance, for the thallium line 5351, but it is probably not in error by more than +/-01 c.c., and the difference may be attributed to the difference of concentration. The apparent orientation polarisation of 2.2 c.c. would give the maximum possible value of the electric dipole moment as 0.3 × 10-18 e.s.u., but since it is of the order which would be expected for the atom polarisation of such a molecule, the moment may be taken to be zero with a high degree of probability.

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