Egelstaff time and the Birnbaum-Cohen line shape

Details Egelstaff time and the Birnbaum-Cohen line shape Egelstaff time and the Birnbaum-Cohen line shape

Apr 1999

adsabs.harvard.edu/cgi-bin/nph-data_query?bibcode=1999aipc..467..482l&link_type=abstract

The 14th international conference on spectral line shapes. AIP Conference Proceedings, Volume 467, pp. 482-484 (1999).

Computer Science

Line And Band Widths, Shapes, And Shifts, Potential Energy Surfaces For Collisions

Scientific paper

Two approaches to constructing line shape functions for fitting collision-induced spectra are examined. Starting with the symmetric time correlation function of Birnbaum and Cohen, we compare the lineshape obtained by including detailed balancing using a Boltzmann factor with that obtained using Egelstaff's complex time (the Birnbaum-Cohen lineshape). The lineshape obtained using Boltzmann-factor asymmetrization is found to be slightly superior in quality of fit to the Birnbaum-Cohen lineshape, and is faster to compute.

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