Effects of Temperature Variations with Height on the Nonequilibrium Populations of Vibrational States of Molecules in Planetary Atmospheres

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The model of the standard problem of radiative transfer in a vibrational-rotational band that we suggested previously (Shved and Semenov, 2001) for a nonlocal thermodynamic equilibrium (non-LTE) in vibrational molecular states is used to study the populations of these states in a nonisothermal planetary atmosphere. The temperature profile in the atmosphere is specified as a temperature perturbation in the form of a Gaussian function that is superimposed on an isothermal atmosphere. We show that the temperature profile has a complex effect on the state populations, which makes it difficult to analytically represent this effect. We investigate the influence of the peculiar features of the temperature profile in an LTE layer on the non-LTE height and suggest a criterion for determining those features that weakly affect this height. Using the populations of the CO2 0110 and 0001 states in the atmospheres of the Earth and Mars as examples, we show that the formulas suggested for estimating the non-LTE height are efficient.

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