Effect of biodegradation on vanadylporphyrin distribution

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Scientific paper

Oils, tars, and degraded oils of varying degrees of biodegradation occur in the Permian Phosphoria Formation along the eastern flank of the Wind River mountains, Wyoming, USA. Biodegradation has altered the isomer distributions of steranes, the hopanes, and the mono- and triaromatised steroids in these oils. The conventional maturity parameters based on these biomarkers are of limited use in estimating their maturity. On the other hand, even in severely biodegraded oils the vanadylporphyrin distributions are unaltered. Because of this, the Porphyrin Maturity Parameter (PMP) derived from the vanadylporphyrin distribution is an ideal parameter for estimating the maturity of these oils. This study also confirms the previous observation that T s and T m are unaffected by even severe biodegradation.

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