Dynamics of the reaction of C(+) with HCl

Details Dynamics of the reaction of C(+) with HCl Dynamics of the reaction of C(+) with HCl

Dec 1988

adsabs.harvard.edu/cgi-bin/nph-data_query?bibcode=1988apj...335..491s&link_type=abstract

Astrophysical Journal, Part 1 (ISSN 0004-637X), vol. 335, Dec. 1, 1988, p. 491-497. DOE-supported research.

Astronomy and Astrophysics

Astrophysics

2

Carbon, Hydrochloric Acid, Interstellar Chemistry, Ion Beams, Molecular Interactions, Reaction Kinetics, Beam Interactions, Heat Of Formation, Kinetic Energy

Scientific paper

This paper presents the results of crossed ion-molecular beam studies of energy and angular distributions for the reaction of C+ with HCl at relative collision energies of 0.51 and 0.88 eV. The reaction appears to be direct, proceeding on a time scale short compared to the rotational period of the transient intermediate complex. The widths of the product kinetic energy distributions are at least 6 eV, indicating that the reaction enthalpy is approximately 5.1 eV. This result is consistent with a bond dissociation energy and heat of formation for the CCl+ product between 219 and 228 kCal mol-1 and 230 - 239 kCal mol-1, respectively.

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