Dissociative recombination of NO+

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Dissociation And Dissociative Attachment By Electron Impact, Oscillator Strengths, Lifetimes, Transition Moments, Other Instrumentation And Techniques For Atomic And Molecular Physics, Mars

Scientific paper

Cross sections for dissociative recombination and dissociative excitation of NO+ in the vibrational ground state have been measured at a heavy-ion storage ring. Branching ratios for dissociative recombination into different electronic states of the atomic fragments have also been determined by an imaging technique. More than 80% of the dissociative recombination events at E = 0 eV produced N(2D) + O(3P). The rotational temperature of the NO+ ion beam was changed by a factor of 2 by employing different types of ion sources. The branching ratios and the dissociative recombination cross section as a function of energy were independent of the rotational temperature. The dissociative recombination cross section was proportional to E-1 at low energies and had peaks in the energy regions 3-8 eV and 10-16 eV. We obtain a total dissociative recombination rate α = 4×10-7 cm3/s at T=300 K for NO+ in the vibrational ground state.

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