Determination of vibrational CO2 distributions in thermodynamically-nonequilibrated rarefied flows by use of radiational characteristics in the 15-micron band

Statistics – Computation

Scientific paper

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Carbon Dioxide Lasers, Gasdynamic Lasers, Infrared Lasers, Nonequilibrium Thermodynamics, Vibrational Spectra, Laser Cavities, Radiant Flux Density, Spectral Bands, Spectral Energy Distribution

Scientific paper

A method for determination of the vibrational distributions and populations of individual vibrational levels of vibrationally nonequilibrated carbon dioxide in bend-stretch manifold and asymmetric stretching mode was developed and substantiated. The method is based on the measurements of integrated radiation intensity in the wide spectral intervals of the 15-micron CO2 band and total emissivities of its appropriate Q-branches. Computations of radiation intensities and emissivities in P and R-branches were performed by using vibrational-rotational band models and in Q-branches by the direct 'line-by-line' integration. It was shown that vibrational temperature of CO2 asymmetric stretching mode may be determined from the measurements of integrated radiation intensity of the 15-micron band. The populations of individual levels of the bend-stretch manifold may be obtained from the measurements of total emissivities of some Q-branches of the 15-micron band. The procedure of the CO2 lower-vibrational-level population determination under the conditions typical of 18-micron and 9-11-micron CO2 laser cavities is described.

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