Computer Science
Scientific paper
Jun 2011
adsabs.harvard.edu/cgi-bin/nph-data_query?bibcode=2011mss..confemh05l&link_type=abstract
"International Symposium On Molecular Spectroscopy, 66th Meeting, Held 20-24 June, 2011 at Ohio State University. http://molspec
Computer Science
Microwave
Scientific paper
The microwave spectrum of the 36Ar-cyclopentanone van der Waals complex has been observed and assigned. The rotational constants are A = 2616.10 MHz, B = 1176.62 MHz, and C = 1022.089 MHz. The results of microwave spectra of the seven isotopomers of the argon-40 cyclopentanone and eight isotopomers of the neon-20 (including 22Ne) cyclopentanone van der Waals complexes in the ground vibrational state have already been reported. The structures of both the argon and neon complexes were determined using extreme Kraitchman analysis. The coordinates of the Ne-20 and Ne-22 isotopologues are nearly equal in the principal axis system of the monomer. Also, the coordinates of the Ar-36 and Ar-40 isotopologues are nearly equal in the principal axis system of the monomer. These results will be discussed in terms of the vibrational averaging in the ground vibrational states of the large amplitude van der Waals vibrations.
Brooks Andrew H.
Duong Chinh H.
Frohman Daniel J.
Lin Wei
Minei Rea J.
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