Determination of radiative lifetimes in neutral arsenic using time-resolved laser spectroscopy in the VUV region

Astronomy and Astrophysics – Astrophysics

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Arsenic, Far Ultraviolet Radiation, Laser Spectroscopy, Radiative Lifetime, Resonance Lines, Absorption Spectroscopy, Molecular Energy Levels, Oscillator Strengths

Scientific paper

Inspired by the recent Hubble Space Telescope first observations of arsenic in an astrophysical object, we have determined the natural radiative lifetime of the upper states of two of the three resonance lines of As I. Short pulse laser excitation at 193.7 nm and 197.2 nm was achieved using different nonlinear optical mixing schemes. Using time-resolved spectroscopy, we obtain tau(4P2 5s 4P3/2) = 4.3(5) ns and tau(4p2 5s 4P1/2) = 4.5(5) ns, yielding the absorption oscillator strengths fabs (193.7 nm) = 0.123(17) and fabs (197.2 nm) = 0.059(8).

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