Detection of a polycyclic aromatic molecule in comet P/Halley

Astronomy and Astrophysics – Astrophysics

Scientific paper

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Chemical Composition, Emission Spectra, Halley'S Comet, Line Spectra, Phenanthrene, Polycyclic Aromatic Hydrocarbons, Spectral Signatures, Astronomical Spectroscopy, Chemical Evolution, Interstellar Matter, Laser Induced Fluorescence, Nebulae, Spectrometers, Vega Project, Comets, Halley, Spectroscopy, Spacecraft Observations, Vega 2 Mission, Emissions, Phenanthrene, Molecules, Fluorescence, Laboratory Studies, Comparison, Experiments, Intensity, Organic Material, Comae, Spectra, Excitation, Calculations, Pr

Scientific paper

New spectroscopic data obtained with the three-channel spectrometer of Vega 2 show, after subtracting the dust-scattered solar continuum, that a broad band emissive feature between 342 and 375 nm progressively arises. Four bands at 347, 356, 364 and 374 nm can be identified in this feature. The 1/p type intensity increase (p: projected distance between nucleus and line of sight) shows that the molecules responsible for the emission are most probably of the parent-type. A search for a molecule emitting fluorescence bands between 342 and 375 nm showed that phenanthrene was a possible candidate. A laser-induced fluorescence experiment was conducted in the laboratory to record the dispersed emission spectrum of phenanthrene under jet-cooled conditions. An excellent agreement was obtained between the cometary and laboratory spectra, for both the wavelength positions of the main peaks and their relative intensities. Present observations are coherent with the detection by IKS of an IR band at 3.28 nm assigned to an X-CH organic compound. The identification of a polycylic aromatic hydrocarbon (PAH) in Halley's comet emphasized the similarities between the material released by comets and diffuse interstellar nebulae. It adds a strong argument in favor of the fact that comets would be constituted of interstellar material.

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