Depth Profiles of Cosmogenic Noble Gases in the Chondrite Knyahinya

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Chondrites, Cosmogenic Nuclides, Exposure Ages, Knyahinya, Noble Gases, Primordial Rare Gas

Scientific paper

Concentrations and isotopic ratios of Ne, Ar, Kr, and Xe have been analyzed in 5-g size samples from different positions within the L5 chondrite Knyahinya. A previous work [1] has shown that Knyahinya experienced a single-stage exposure history (duration 40.5 Ma) as a meteoroid of approximately spherical shape (radius 45 cm). For these reasons, this meteorite represents a very interesting object to study depth profiles of cosmogenic nuclide concentrations and to test and improve model calculations of production rates. The procedure of extraction of noble gases adopted for this work, includes two pyrolyses respectively at about 450 degrees C and 650 degrees C, followed by a combustion step in pure O2 (15-25 torr pressure) at 650 degrees C before the complete melting of the sample [2]. This procedure allows a low-temperature extraction of a significant fraction of the Kr and Xe trapped noble gas component, leading to an enrichment of the cosmogenic component during the last temperature step. Concentration of trapped Ar, Kr, and Xe is 2-3 times lower than expected for a type 5 chondrite. The isotopic composition of the trapped Xe component analyzed in the combustion step is identical with the OC- Xe composition measured in Forest Vale [3]. Preliminary results show that concentration of cosmogenic 83Kr increases by 16% from the surface to the center when the ratio of cosmogenic 78Kr to 83Kr decreases from 0.157 to 0.136. The concentration of 81Kr has been measured in each sample. It increases from 0.0220 10^-12 cm^3 STP/g near the surface to 0.0255 10^-12 cm^3 STP/g at the center, in excellent agreement with the variations measured by Eugster [4] in other ordinary chondrites. Acknowledgments: This work was supported by C.N.R.S., by IN2P3 and by INSU (Programme National de Planetologie). References: [1] Graf Th. et al. (1990) GCA, 54, 2511-2520. [2] Gilabert E. and Lavielle B. (1991) Meteoritics, 26, 337. [3] Lavielle B. and Marti K. (1992) JGR, 97, 20875-20881. [4] Eugster O. (1988) GCA, 52, 1649-1662.

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