Creation of Population Inversions in the Λ Doublets of OH by the Photodissociation of H2O at 157 nm: A Possible Mechanism for the Astronomical Maser

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Diffuse Spectra, Predissociation, Photodissociation, Radio-Frequency And Microwave Spectra, Radiation Mechanisms, Polarization

Scientific paper

Water molecules are photolyzed by a F2 laser at 157 nm. The nascent OH (2Π32, v=0) rotational state distribution, probed via laser-induced fluorescence, reveals a strong preference for populating the upper Λ-doublet component. The population inversion is found to be a function of both the initial temperature of the H2O as well as the final rotational state in which the OH radical is formed. These results may provide a simple mechanism for the astronomical OH maser observed by others.

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