Condensation Coefficients of Mercury Halides

Details Condensation Coefficients of Mercury Halides Condensation Coefficients of Mercury Halides

Sep 1938

adsabs.harvard.edu/cgi-bin/nph-data_query?bibcode=1938natur.142..572m&link_type=abstract

Nature, Volume 142, Issue 3595, pp. 572 (1938).

Computer Science

Scientific paper

USING the method of Alty1, we have measured the coefficients of condensation (f) of the compounds mercuric chloride, bromide and iodide. A hemispherical cap of these salts was deposited by sublimation on the end of a glass tube which could be heated internally by boiling turpentine. The temperature of the cap surface was measured by a fine thermocouple while the salt evaporated in a high vacuum. The quantity of salt evaporated per unit time and area (M1) was determined by weighing the deposit on a surrounding glass tube immersed in liquid air. By calculating the maximum rate of evaporation (M2) from the formula of the kinetic theory of gases, where P is saturated vapour pressure (mm. mercury), M is molecular weight, t is time of evaporation, T is absolute temperature, one finds f = M1/M2.

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