Computer Science
Scientific paper
Oct 2005
adsabs.harvard.edu/cgi-bin/nph-data_query?bibcode=2005gecoa..69.4747b&link_type=abstract
Geochimica et Cosmochimica Acta, Volume 69, Issue 20, p. 4747-4757.
Computer Science
Scientific paper
Southern Ocean aerosols were collected at the Cape Grim Baseline Air Pollution Station from onshore air under baseline conditions between February 1999 and April 2000. Thermal ionization techniques (TIMS) and isotope dilution mass spectrometry (IDMS) were used to measure the isotopic composition and concentration of lead in the air giving concentrations as low as 0.6 ± 0.1 pg · m-3. Air collected under baseline conditions for 12 months (May 1999 April 2000) yielded an overall lead concentration of 11.0 ± 0.2 pg · m-3 and isotopic composition of 206Pb/207Pb = 1.154, 208Pb/207Pb = 2.387 and 206Pb/204Pb = 17.93. The range in isotopic ratios was consistent with the mixing of lead from major population centers in the Southern Hemisphere in the mid to high latitudes, except for the presence of highly radiogenic lead in some samples. Contributions from radiogenic lead of up to ˜0.8% were observed. Three periods with the highest percentage contribution of radiogenic lead (>0.5%) were investigated in more detail, and 4-d back-trajectories and radon concentrations were used to help identify the sources. The sources are probably associated with the mining and processing of uranium rich ores in southern Africa and possibly South Australia.
Bollhöfer A. F.
Burton Graeme R.
Chisholm W.
Dick Alan L.
Loss Robert D.
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