Complete active space self-consistent field calculations of the vibrational band strengths for C3

Astronomy and Astrophysics – Astrophysics

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Carbon Stars, Stellar Atmospheres, Transition Probabilities, Vibrational Spectra, Absorption Spectra, Dipole Moments, Molecular Energy Levels, Opacity

Scientific paper

Complete active space self-consistent calculations of the energy and dipole moment functions were carried out for C3 in its electronic ground state. The absorption coefficient between 0.7 and 75 microns is calculated on the basis of the vibrational band strength of transitions between the 800 lowest states with v less than or equal to (4, 39, 3). In cool carbon stars with a high C/O ratio, C3 is found to be the most prevalent of the known opacity sources.

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