Collisional excitation rates of H2O with H2 . I. Pure rotational excitation rates with para-H2 at very low temperature

Astronomy and Astrophysics – Astrophysics

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Molecular Data, Molecular Processes

Scientific paper

Close coupling (CC) calculations of pure rotational excitation rates of H2O by para-H2 are performed between 5 K and 20 K. Some discrepancies with Phillips et al. (\cite{phillips95}, \cite{phillips96}) are found and explained. We find that the presence of resonances greatly influences the excitation rates at very low temperature. Fits of our collisional rates are provided.

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