Coherence-Detected Ftmw-Ir Spectroscopy of CH_3OD in the OD Stretch Region.

Details Coherence-Detected Ftmw-Ir Spectroscopy of CH_3OD in the OD Stretch Region. Coherence-Detected Ftmw-Ir Spectroscopy of CH_3OD in the OD Stretch Region.

Jun 2009

adsabs.harvard.edu/cgi-bin/nph-data_query?bibcode=2009mss..confemg05t&link_type=abstract

"International Symposium On Molecular Spectroscopy, 64th Meeting, Held 22-26 June, 2009 at Ohio State University. http://molspec

Computer Science

Infrared/Raman

Scientific paper

Infrared spectra of the connected rotational levels of jet-cooled CH_3OD are recorded in the OD stretch region. The observed spectra in the range 2710 - 2740 cm^{-1} result from E-species transitions (3_0← 3_{-1},2_0← 3_1,1_0← 1_1) of CH_3OD. For the available rotational levels (K {'} = 0 , K {'} = 1 and K {'} = 2), the reduced torsional energies follow a pattern similar to the ground state. The torsional tunneling splitting in the OD stretch excited state is deduced to be 2.4 cm^{-1} as compared to 2.6 cm^{-1} in the ground state.

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