Chemical model calculations of C2, C3, CH, CN, OH, and NH2 abundances in cometary comae

Astronomy and Astrophysics – Astrophysics

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Abundance, Carbon, Chemical Reactions, Comets, Hydrocarbons, Molecular Interactions, Ammonia, Astronomical Models, Chemical Composition, Comet Nuclei, Cyanides, Hydroxyl Radicals, Interstellar Matter

Scientific paper

One-dimensional radial models of the chemistry in cometary comae have been constructed using a comprehensive system of chemical reactions for a number of assumed nuclear compositions. Column abundances for C2, C3, CR, OH, CN, and NH2 calculated from these models are compared to those calculated from observations. Models which assume a parent volatile mixture consisting of the simplest species containing carbon, oxygen, and nitrogen -- H2O, CO2, CR4, and NH3 -produce column abundances of C2, OH, CR, and NH2 consistent with observations but do not produce sufficient amounts of C3 and CN. Models which assume a more complex mixture of parent volatiles, derived by assuming comets originate from a gas with composition similar to that found in interstellar molecular clouds, are successful in accounting for the observed coma column abundances of C2, C3, CN, CR, OH, and NH2.

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