Characteristic feature of 2p - 2s transition in spherically confined hydrogen atom

Astronomy and Astrophysics – Astronomy

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Scientific paper

The electronic transition 2p - 2s absent in the free hydrogen atom due to the Coulomb degeneracy becomes feasible when the atom is embedded inside a spherical cavity with impenetrable walls. We show, for the first time, that the oscillator strength corresponding to this transition in the confined state attains its maximum value at the characteristic confinement radius of 2 a.u. at which simultaneous degeneracy also takes place between the confined [ns,(n+1)d] levels with n >= 2.

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