Characterisation of fossil porphyrins of the "di-DPEP" type

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Scientific paper

Four basic structural types of alkyl porphyrins have been reported frequently to occur in sedimentary organic matter as metallocomplexes. The purpose of this note is: i) to report the structural assignment of two representatives (C 32 , C 33 ) of the so-called "di-DPEP" series, isolated from El Lajjun shale, a bituminous limestone of central Jordan (Upper Cretaceous, El Lajjun Basin); ii) to evaluate a previous suggestion that this type of compound and sedimentary monobenzoporphyrins are related in structure and origin.

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