Computer Science
Scientific paper
Jun 2010
adsabs.harvard.edu/cgi-bin/nph-data_query?bibcode=2010mss..confere07t&link_type=abstract
"International Symposium On Molecular Spectroscopy, 65th Meeting, Held 21-25 June, 2010 at Ohio State University. http://molspec
Computer Science
Radicals And Ions
Scientific paper
Very few spectroscopic data of tri-substituted benzene are available in the literature. We applied the resonant two-photon ionization and mass analyzed threshold ionization spectroscopic techniques to record the vibronic and cation spectra of 3,4-difluoroaniline. The results give precise electronic excitation and adiabatic ionization energies. In addition, information about the active vibrations in the first electronically excited and cationic ground states are also obtained. The spectral assignment has been successfully done by comparing the present data with those of m-fluoroaniline and p-fluoroaniline. We have performed theoretical calculations to support our experimental findings. Keywords: 3,4-difluoaniline, resonant multiphoton ionization, threshold ionization, cation spectra
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