Cation distribution and exsolution in the Luna-20 pyroxenes as the chronological indicator of their thermal history

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Geochronology, Lunar Temperature, Lunik 20 Lunar Probe, Pyroxenes, Cations, Diffraction Patterns, Electron Microscopy, Lunar Geology, Microstructure, Photomicrographs, Solid Phases, X Ray Analysis

Scientific paper

Data on the structural and phase states of Lunar-20 pyroxenes are presented which were obtained by a combination of techniques involving X-ray structural analysis, electron microscopy, and X-ray microprobe analysis. The kinetics of Fe(2+)-Mg ordering in orthopyroxenes is discussed along with the kinetics of exsolution in clinopyroxenes and cooling rates for both types of pyroxene. A method for the approximate estimation of the subsolidus cooling rate is proposed which is based on analysis of the kinetics of solid-phase reactions in pyroxenes. Experimental results for three clinopyroxene and two orthopyroxene crystals from the Luna-20 regolith are presented, the thermal history of these pyroxenes is considered, and the pyroxenes are classified according to their thermal history as slowly cooled, rapidly cooled, and those with a complicated thermal history. It is concluded that most of the pyroxenes in the Luna-20 samples are characterized by slow subsolidus cooling and represent material excavated from deeper parts of the lunar crust by the Amegino crater event.

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