Carbon isotopic variation within individual diamonds

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Abundance, Carbon Isotopes, Diamonds, Geochemistry, Carbon Dioxide, Carbon 12, Carbon 13, Chemical Fractionation, Crystal Growth, Impurities, Isotopic Enrichment, Laser Cutting

Scientific paper

The intra-specimen distribution of carbon isotope abundance in type I diamonds was studied by a sealed tube technique. The cores of the diamonds were found to be isotopically light, i.e., enriched in C-12, while the isotopic mass increased outwards. The variations amounted to 4 parts per thousand for carbon liberated above 600 C. Further studies were performed with 47 laser-cut samples to determine the concentrations of other impurities, with the finding of no definite pattern of other distribution anomalies. It is suggested that the skewed delta C-13 distribution arose from injection of carbon from isotopically distinct reservoirs. The data are consistent with a carbon dioxide source with formation occurring according to a Rayleigh distribution process.

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