Other
Scientific paper
Nov 2011
adsabs.harvard.edu/cgi-bin/nph-data_query?bibcode=2011gecoa..75.7081t&link_type=abstract
Geochimica et Cosmochimica Acta, Volume 75, Issue 22, p. 7081-7098.
Other
Scientific paper
Pore fluid calcium isotope, calcium concentration and strontium concentration data are used to measure the rates of diagenetic dissolution and precipitation of calcite in deep-sea sediments containing abundant clay and organic material. This type of study of deep-sea sediment diagenesis provides unique information about the ultra-slow chemical reactions that occur in natural marine sediments that affect global geochemical cycles and the preservation of paleo-environmental information in carbonate fossils. For this study, calcium isotope ratios (δ 44/40 Ca) of pore fluid calcium from Ocean Drilling Program (ODP) Sites 984 (North Atlantic) and 1082 (off the coast of West Africa) were measured to augment available pore fluid measurements of calcium and strontium concentration. Both study sites have high sedimentation rates and support quantitative sulfate reduction, methanogenesis and anaerobic methane oxidation. The pattern of change of δ 44/40 Ca of pore fluid calcium versus depth at Sites 984 and 1082 differs markedly from that of previously studied deep-sea Sites like 590B and 807, which are composed of nearly pure carbonate sediment. In the 984 and 1082 pore fluids, δ 44/40 Ca remains elevated near seawater values deep in the sediments, rather than shifting rapidly toward the δ 44/40 Ca of carbonate solids. This observation indicates that the rate of calcite dissolution is far lower than at previously studied carbonate-rich sites. The data are fit using a numerical model, as well as more approximate analytical models, to estimate the rates of carbonate dissolution and precipitation and the relationship of these rates to the abundance of clay and organic material. Our models give mutually consistent results and indicate that calcite dissolution rates at Sites 984 and 1082 are roughly two orders of magnitude lower than at previously studied carbonate-rich sites, and the rate correlates with the abundance of clay. Our calculated rates are conservative for these sites (the actual rates could be significantly slower) because other processes that impact the calcium isotope composition of sedimentary pore fluid have not been included. The results provide direct geochemical evidence for the anecdotal observation that the best-preserved carbonate fossils are often found in clay or organic-rich sedimentary horizons. The results also suggest that the presence of clay minerals has a strong passivating effect on the surfaces of biogenic carbonate minerals, slowing dissolution dramatically even in relation to the already-slow rates typical of carbonate-rich sediments.
Depaolo Donald J.
Turchyn Alexandra V.
No associations
LandOfFree
Calcium isotope evidence for suppression of carbonate dissolution in carbonate-bearing organic-rich sediments does not yet have a rating. At this time, there are no reviews or comments for this scientific paper.
If you have personal experience with Calcium isotope evidence for suppression of carbonate dissolution in carbonate-bearing organic-rich sediments, we encourage you to share that experience with our LandOfFree.com community. Your opinion is very important and Calcium isotope evidence for suppression of carbonate dissolution in carbonate-bearing organic-rich sediments will most certainly appreciate the feedback.
Profile ID: LFWR-SCP-O-738679